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1

Lanthanide(III) Complexes of DOTA–Glycoconjugates: A Potential New Class of Lectin-Mediated Medical Imaging Agents

João P. André, Carlos F. G. C. Geraldes, José A. Martins, André E. Merbach, Maria I. M. Prata, Ana C. Santos, João J. P. de Lima, Éva Tóth

Journal:

Chemistry - A European Journal

Year:

2004

Language:

english

File:

PDF, 406 KB

english, 2004

2

Gadolinium-based linear polymer with temperature-independent proton relaxivities: a unique interplay between the water exchange and rotational contributions

Éva Tóth, Ingrid van Uffelen, Lothar Helm, André E. Merbach, David Ladd, Karen Briley-Sæbø, Kenneth E. Kellar

Journal:

Magnetic Resonance in Chemistry

Year:

1998

Language:

english

File:

PDF, 301 KB

english, 1998

3

Water-Exchange Mechanism of Tetraaquapalladium(II). A Variable-Pressure and Variable-Temperature Oxygen-17 NMR Study

Lothar Helm, Lars I. Elding, André E. Merbach

Journal:

Helvetica Chimica Acta

Year:

1984

Language:

english

File:

PDF, 404 KB

english, 1984

4

Water Contributes Actively to the Rapid Crossing of a Protein Unfolding Barrier

Maik H Jacob, Christophe Saudan, Georg Holtermann, Andreas Martin, Dieter Perl, André E Merbach, Franz X Schmid

Journal:

Journal of Molecular Biology

Year:

2002

Language:

english

File:

PDF, 212 KB

english, 2002

5

Structural and Dynamic Parameters Obtained from 17 O NMR, EPR, and NMRD Studies of Monomeric and Dimeric Gd 3+ Complexes of Interest in Magnetic Resonance Imaging: An Integrated and Theoretically Self-Consistent Approach 1

Powell, D. Hugh, Dhubhghaill, Orla M. Ni, Pubanz, Dirk, Helm, Lothar, Lebedev, Yakob S., Schlaepfer, Willi, Merbach, André E.

Journal:

Journal of the American Chemical Society

Year:

1996

Language:

english

File:

PDF, 324 KB

english, 1996

6

High-Pressure Stopped-Flow Spectrometer for Kinetic Studies of Fast Reactions by Absorbance and Fluorescence Detection

Bugnon, Pascal, Laurenczy, Gábor, Ducommun, Yves, Sauvageat, Pierre-Yves, Merbach, André E., Ith, Roger, Tschanz, René, Doludda, Michael, Bergbauer, Rolf, Grell, Ernst

Journal:

Analytical Chemistry

Year:

1996

Language:

english

File:

PDF, 175 KB

english, 1996

7

First 17 O NMR Observation of Coordinated Water on Both Isomers of [Eu(DOTAM)(H 2 O)] 3+ : A Direct Access to Water Exchange and its Role in the Isomerization 1

Dunand, Frank A., Aime, Silvio, Merbach, André E.

Journal:

Journal of the American Chemical Society

Year:

2000

Language:

english

File:

PDF, 117 KB

english, 2000

8

Syntheses and Crystal and Molecular Structures of the Hexakis(N,N-dimethylformamide) Complexes of Ruthenium(II) and Ruthenium(III)

Judd, Robert J., Cao, Renhai, Biner, Margret, Armbruster, Thomas, Buergi, Hans-Beat, Merbach, Andre E., Ludi, Andreas

Journal:

Inorganic Chemistry

Year:

1995

Language:

english

File:

PDF, 541 KB

english, 1995

9

Water exchange on magnesium(II) in aqueous solution: a variable temperature and pressure 17O NMR study

Anne Bleuzen, Pierre-André Pittet, Lothar Helm, André E. Merbach

Journal:

Magnetic Resonance in Chemistry

Year:

1997

Language:

english

File:

PDF, 385 KB

english, 1997

10

Coordination equilibrium— a clue for fast water exchange on potential magnetic resonance imaging contrast agents?

Éva Tóth, Orla M. Ni Dhubhghaill, Ghislaine Besson, Lothar Helm, André E. Merbach

Journal:

Magnetic Resonance in Chemistry

Year:

1999

Language:

english

File:

PDF, 111 KB

english, 1999

11

17O-NMR, EPR and NMRD Characterization of [Gd(DTPA-BMEA)(H2O)]: A Neutral MRI Contrast Agent

Éva Tóth, Fabienne Connac, Lothar Helm, Kofi Adzamli, André E. Merbach

Journal:

European Journal of Inorganic Chemistry

Year:

1998

Language:

english

File:

PDF, 171 KB

english, 1998

12

Spectroscopic Study of the Hydration Equilibria and Water Exchange Dynamics of Lanthanide(III) Complexes of 1,7-Bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane (DO2A)

Fabrice Yerly, Frank A. Dunand, E´´va Tóth, Artur Figueirinha, Zoltán Kovács, A. Dean Sherry, Carlos F. G. C. Geraldes, André E. Merbach

Journal:

European Journal of Inorganic Chemistry

Year:

2000

Language:

english

File:

PDF, 315 KB

english, 2000

13

Complete Carbonylation of fac-[Tc(H2O)3(CO)3]+ under CO Pressure in Aqueous Media: A Single Sample Story!

Nicolas Aebischer, Roger Schibli, Roger Alberto, André E. Merbach

Journal:

Angewandte Chemie

Year:

2000

Language:

english

File:

PDF, 111 KB

english, 2000

14

Gd(DTPA-bisamide)alkyl Copolymers: A Hint for the Formation of MRI Contrast Agents with Very High Relaxivity

Éva Tóth, Lothar Helm, Kenneth E. Kellar, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

1999

Language:

english

File:

PDF, 204 KB

english, 1999

15

High Relaxivity for Monomeric Gd(DOTA)-Based MRI Contrast Agents, Thanks to Micellar Self-Organization

João P. André, Éva Tóth, Holger Fischer, Anna Seelig, Helmut R. Mäcke, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

1999

Language:

english

File:

PDF, 194 KB

english, 1999

16

Complete Carbonylation of fac-[Tc(H2O)3(CO)3]+ under CO Pressure in Aqueous Media: A Single Sample Story!

Nicolas Aebischer, Roger Schibli, Roger Alberto, André E. Merbach

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 118 KB

english, 2000

17

Synthesis, Variable Temperature and Pressure 17O NMR Study of Bis(alkylamide) Derivatives of [(Gd-DTPA)(H2O)]2− − An Assessment of the Substitution Effect on Water Exchange Kinetics

François Botteman, Gaëlle M. Nicolle, Luce Vander Elst, Sophie Laurent, André E. Merbach, Robert N. Muller

Journal:

European Journal of Inorganic Chemistry

Year:

2002

Language:

english

File:

PDF, 178 KB

english, 2002

18

Solution and Solid-State Characterization of EuII Chelates: A Possible Route Towards Redox Responsive MRI Contrast Agents

László Burai, Éva Tóth, Sabine Seibig, Rosario Scopelliti, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2000

Language:

english

File:

PDF, 282 KB

english, 2000

19

Cover Picture

Olimpia Mamula, Florence J. Monlien, Alain Porquet, Gérard Hopfgartner, André E. Merbach, Alex von Zelewsky

Journal:

Chemistry - A European Journal

Year:

2001

File:

PDF, 22 KB

2001

20

Molecular Dynamics Simulations of MRI-Relevant GdIII Chelates: Direct Access to Outer-Sphere Relaxivity

Alain Borel, Lothar Helm, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2001

Language:

english

File:

PDF, 179 KB

english, 2001

21

Self-Assembly of Multinuclear Coordination Species with Chiral Bipyridine Ligands: Silver Complexes of 5,6-CHIRAGEN(o,m,p-xylidene) Ligands and Equilibrium Behaviour in Solution

Olimpia Mamula, Florence J. Monlien, Alain Porquet, Gérard Hopfgartner, André E. Merbach, Alex von Zelewsky

Journal:

Chemistry - A European Journal

Year:

2001

Language:

english

File:

PDF, 291 KB

english, 2001

22

Towards Rational Design of Fast Water-Exchanging Gd(dota-Like) Contrast Agents? Importance of the M/m Ratio

Frank A. Dunand, Rachel S. Dickins, David Parker, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2001

Language:

english

File:

PDF, 332 KB

english, 2001

23

The Impact of Rigidity and Water Exchange on the Relaxivity of a Dendritic MRI Contrast Agent

Gaëlle M. Nicolle, Éva Tóth, Heribert Schmitt-Willich, Bernd Radüchel, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 310 KB

english, 2002

24

Molecular Dynamics Simulation of [Gd(egta)(H2O)]− in Aqueous Solution: Internal Motions of the Poly(amino carboxylate) and Water Ligands, and Rotational Correlation Times

Fabrice Yerly, Kenneth I. Hardcastle, Lothar Helm, Silvio Aime, Mauro Botta, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 366 KB

english, 2002

25

Cover Picture

Fabrice Yerly, Kenneth I. Hardcastle, Lothar Helm, Silvio Aime, Mauro Botta, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 47 KB

english, 2002

26

Aspects of Aqueous Ruthenium(II) Chemistry

Pascal V. Grundler, Gabor Laurenczy, André E. Merbach

Journal:

Helvetica Chimica Acta

Year:

2001

Language:

english

File:

PDF, 349 KB

english, 2001

27

High Relaxivity Confined to a Small Molecular Space: A Metallostar-Based, Potential MRI Contrast Agent

João Bruno Livramento, Éva Tóth, Angélique Sour, Alain Borel, André E. Merbach, Robert Ruloff

Journal:

Angewandte Chemie

Year:

2005

Language:

english

File:

PDF, 427 KB

english, 2005

28

High Relaxivity Confined to a Small Molecular Space: A Metallostar-Based, Potential MRI Contrast Agent

João Bruno Livramento, Éva Tóth, Angélique Sour, Alain Borel, André E. Merbach, Robert Ruloff

Journal:

Angewandte Chemie International Edition

Year:

2005

Language:

english

File:

PDF, 428 KB

english, 2005

29

Mechanisms of Water Exchange between Lanthanide(III) Aqua Ions [Ln(H2O)n]3+ and bulk water: A Molecular Dynamics Simulation Approach Including High-Pressure Effects

Thomas Kowall, François Foglia, Lothar Helm, Prof. André E. Merbach

Journal:

Chemistry - A European Journal

Year:

1996

Language:

english

File:

PDF, 1.55 MB

english, 1996

30

The Role of Water Exchange in Attaining Maximum Relaxivities for Dendrimeric MRI Contrast Agents

Éva Tóth, Dirk Pubanz, Sylvain Vauthey, Lothar Helm, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

1996

Language:

english

File:

PDF, 955 KB

english, 1996

31

GdIII Complexes with Fast Water Exchange and High Thermodynamic Stability: Potential Building Blocks for High-Relaxivity MRI Contrast Agents

Sabrina Laus, Robert Ruloff, Éva Tóth, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2003

Language:

english

File:

PDF, 239 KB

english, 2003

32

Towards Binuclear Polyaminocarboxylate MRI Contrast Agents? Spectroscopic and MD Study of the Peculiar Aqueous Behavior of the LnIII Chelates of OHEC (Ln=Eu, Gd, and Tb): Implications for Relaxivity

Gaëlle M. Nicolle, Fabrice Yerly, Daniel Imbert, Ulrike Böttger, Jean-Claude Bünzli, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2003

Language:

english

File:

PDF, 441 KB

english, 2003

33

MD Simulations of Acyclic and Macrocyclic Gd3+-Based MRI Contrast Agents: Influence of the Internal Mobility on Water Proton Relaxivity

Fabrice Yerly, Alain Borel, Lothar Helm, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2003

Language:

english

File:

PDF, 988 KB

english, 2003

34

Novel Macrocyclic EuII Complexes: Fast Water Exchange Related to an Extreme MOwater Distance

László Burai, Éva Tóth, Gilles Moreau, Angélique Sour, Rosario Scopelliti, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2003

Language:

english

File:

PDF, 241 KB

english, 2003

35

Rotational Dynamics Account for pH-Dependent Relaxivities of PAMAM Dendrimeric, Gd-Based Potential MRI Contrast Agents

Sabrina Laus, Angélique Sour, Robert Ruloff, Éva Tóth, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2005

Language:

english

File:

PDF, 374 KB

english, 2005

36

Supramolecular Assembly of an Amphiphilic GdIII Chelate: Tuning the Reorientational Correlation Time and the Water Exchange Rate

Susana Torres, José A. Martins, João P. André, Carlos F. G. C. Geraldes, André E. Merbach, Éva Tóth

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 172 KB

english, 2006

37

A Starburst-Shaped Heterometallic Compound Incorporating Six Densely Packed Gd3+ Ions

João Bruno Livramento, Angélique Sour, Alain Borel, André E. Merbach, Éva Tóth

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 788 KB

english, 2006

38

Unexpected Aggregation of Neutral, Xylene-Cored Dinuclear GdIII Chelates in Aqueous Solution

Jérôme Costa, Edina Balogh, Véronique Turcry, Raphaël Tripier, Michel Le Baccon, Françoise Chuburu, Henri Handel, Lothar Helm, Éva Tóth, André E. Merbach

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 227 KB

english, 2006

39

ChemInform Abstract: High-Pressure NMR Kinetics. Part 89. Nuclear and Electronic Relaxation of Eu2+(aq): An Extremely Labile Aqua Ion.

Peter Caravan, Eva Toth, Antal Rockenbauer, Andre E. Merbach

Journal:

Year:

2000

File:

PDF, 31 KB

2000

40

ChemInform Abstract: Substitution Studies of Second- and Third-Row Transition Metal Oxo Complexes

Andreas Roodt, Amira Abou-Hamdan, Hendrik P. Engelbrecht, Andre E. Merbach

Journal:

Year:

2000

File:

PDF, 25 KB

2000

41

ChemInform Abstract: Similarities and Differences Between the Isoelectronic Gd(III) and Eu(II) Complexes with Regard to MRI Contrast Agent Applications

Eva Toth, Laszlo Burai, Andre E. Merbach

Journal:

Year:

2001

File:

PDF, 26 KB

2001

42

ChemInform Abstract: Applications of Advanced Experimental Techniques: High Pressure NMR and Computer Simulations

Lothar Helm, Andre E. Merbach

Journal:

Year:

2002

File:

PDF, 25 KB

2002

43

Future Perspectives: Applications of High Pressure in Supramolecular Chemistry

Robert Ruloff, Christophe Saudan, Andre E. Merbach, Frank-Gerrit Klarner

Journal:

Year:

2003

File:

PDF, 51 KB

2003

44

Molecular Dynamics of Gd(III) Complexes in Aqueous Solution by HF EPR

Alain Borel, Lothar Helm, Andre E. Merbach

Journal:

Year:

2005

File:

PDF, 8 KB

2005

45

Inorganic and Bioinorganic Solvent Exchange Mechanisms

Lothar Helm, Andre E. Merbach

Journal:

Year:

2005

File:

PDF, 8 KB

2005

46

In vivo MRI assessment of a novel GdIII-based contrast agent designed for high magnetic field applications

Paulo Loureiro de Sousa, João Bruno Livramento, Lothar Helm, André E. Merbach, William Même, Bich-Thuy Doan, Jean-Claude Beloeil, Maria I. M. Prata, Ana C. Santos, Carlos F. G. C. Geraldes, Éva Tóth

Journal:

Contrast Media & Molecular Imaging

Year:

2008

Language:

english

File:

PDF, 341 KB

english, 2008

47

Lanthanide(III) Chelates of DTPA Bis(amide) Glycoconjugates: Potential Imaging Agents Targeted at the Asyaloglycoprotein Receptor

Paula Baía, João P. André, Carlos F. G. C. Geraldes, José A. Martins, André E. Merbach, Éva Tóth

Journal:

European Journal of Inorganic Chemistry

Year:

2005

Language:

english

File:

PDF, 157 KB

english, 2005

48

A PCP-Pincer RuII–Terpyridine Building Block as a Potential “Antenna Unit” for Intramolecular Sensitization

Marcella Gagliardo, Fabio Rizzo, Martin Lutz, Anthony L. Spek, Gerard P. M. van Klink, André E. Merbach, Luisa De Cola, Gerard van Koten

Journal:

European Journal of Inorganic Chemistry

Year:

2007

Language:

english

File:

PDF, 183 KB

english, 2007

49

Adducts of Niobium(V) and Tantalum(V) Halogenides. IX. Relative stability of the adducts of the chlorides and bromides with some dialkylchalcogenides

René Good, André E. Merbach

Journal:

Helvetica Chimica Acta

Year:

1974

Language:

english

File:

PDF, 364 KB

english, 1974

50

Electron Transfer Spectra of the Hexachloro- and Hexabromoniobate(V) and Tantalate(V) Anions

Mario Valloton, André E. Merbach

Journal:

Helvetica Chimica Acta

Year:

1974

Language:

english

File:

PDF, 652 KB

english, 1974

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